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From Amorphous
Red Phosphorus
to a Few Layers
of Black
Phosphorus: A
Low-cost and
Efficient
Preparation
Process
G. Tiouitchia,b,
F. ElManjlib,c,
O. Mounkachia,
A. Mahmoudd,
F. Boschinie,
A. Karae,
H. Oughaddouf,g,
M. Hamedounb,
A. Benyoussefb,h
and M. Ait
Alic*
a
LaMCScI, B.P.
1014, Faculty of
Science-Mohammed
V University,
Rabat, Morocco.
b
Materials and
Nanomaterials
Center, MAScIR
Foundation,
Rabat Design
Center, Rue
Mohamed Al
Jazouli, Madinat
Al Irfane, Rabat
10 100, Morocco.
c
Coordination
Chemistry
Laboratory, Cadi
Ayyad
University,
Faculty of
Sciences
Semlalia (UCA-FSSM),
B.P. 2390 -
40000 Marrakech,
Morocco.
Email:
aitali@uca.ac.ma
d
Greenmat, Cesam,
Institute of
Chemistry B6,
University of
Liege, 4000
Liège, Belgium.
e
Department of
Physics,
University of
Central Florida,
Orlando, Florida
32816, USA.
f
Institut des
Sciences
Moléculaires
d’Orsay,
ISMO-CNRS, Bât.
210, Université
Paris-Sud, 91405
Orsay, France.
g
Département de
Physique,
Université de
Cergy-Pontoise,
95031
Cergy-Pontoise
Cedex, France.
h
Hassan II
Academy of
Science and
Technology,
Rabat, Morocco.
Doi :
https://doi.org/10.47011/13.2.6
Cited by :
Jordan J. Phys.,
13 (2) (2020)
149-155
PDF
Received
on:
08/08/2019;
Accepted
on:
16/12/2019
Abstract:
In this
work, we
present
an
efficiency
synthesis
method
of
phosphorene
from red
phosphorus
by means
of black
phosphorus.
The
latter
was
synthesized
by using
copper,
tin, tin
iodide
and red
phosphorus
as
precursor
at low
pressure-temperature.
Characterizations
with
powder
X-ray
diffraction,
scanning
electron
microscopy
(SEM),
energy
dispersive
spectrometry
(EDX),
high-resolution
TEM
(HR-TEM)
and
Raman
spectroscopy
were
performed
to
confirm
the high
quality
and
purity
of black
phosphorus
crystal.
Liquid
phase
method
was used
to
exfoliate
black
phosphorus
to
phosphorene
in
N-methyl-2-pyrrolidone
(NMP) as
solvent.
Atomic
force
microscopy
and STEM
were
used to
confirm
the
exfoliation
of black
phophorus
in a few
layers
of
phophorene.
Keywords:
2D
materials,
Red
phosphorus,
Black
phosphorus,
Phosphorene,
Liquid-phase
exfoliation.
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